Prof. Dr. Takanori Fukushima
Takanori Fukushima
Professor, Inorganic Resources Division, Chemical Resorces Laboratory, Titech
fukushima[at]res.titech.ac.jp
Education
1988–1992 | B.Sc. Tohoku University |
1992–1994 | M.Sc. Tohoku University |
1994–1996 | Ph.D. Tohoku University |
1999 | D.Sci. Tohoku University |
Academic Career
1995–1996 | Research Fellow, Japan Society for the Promotion of Science |
1996–2001 | Assistant Professor, Tohoku University |
2001–2004 | Researcher, ERATO Aida Nanospace Project, Japan Science and Technology Corporation |
2004–2011 | Group Leader, ERATO Aida Nanospace Project, Japan Science and Technology Agency |
2007–2010 | Team Leader, Functional Soft Matter Engineering Team, RIKEN |
2010–2013 | Team Leader, Energy Conversion Research Team, RIKEN |
2010–2016 | Professor, Chemical Resources Laboratory, Tokyo Institute of Technology |
2016–Present | Professor, Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology | 2024–Present | Director, Research Center for Autonomous Systems Materialogy, Institute of Innovative Research, Tokyo Institute of Technology |
Awards
2005 Wiley Award, The Society of Polymer Science, Japan
2008 The Young Scientists's Prize for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology
2010 Asian Core Program Lectureship Award in the 5th International Conference Cutting-Edge of Organic Chemistry in Asia, ICCEOCA
2012 Nagase Award
2015 Seiichi Tejima Paper Award
2016 38th JSAP Outstanding Paper Award
2020 Seiichi Tejima Paper Award
2020 The Award for Science and Technology, The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology
2020 42th JSAP Outstanding Paper Award
2021 The Award of the Society of Polymer Science, Japan
Recent Publications
- Single-Molecule Observation of Redox Reactions Enabled by Rigid and Isolated Tripodal Molecules
Y. Kobayashi, Y. Yokota, R. A. Wong, M. Hong, J. Takeya, S. Osawa, F. Ishiwari, Y. Shoji, T. Harimoto, K. Sugimoto, Y. Ishigaki, T. Suzuki, T. Fukushima, Y. Kim
J. Phys. Chem. C 2022, in press (DOI: 10.1021/acs.jpcc.2c07362).
- Synthesis, physical properties, and OFET
characteristics of a propeller-shaped molecule with a dithiarubicene blade
K. Tsukamoto, K. Takagi, S. Jinnai, Y. Ie, M. Hara, T. Fukushima
Mol. Syst. Des. Eng. 2022, 7, 1639–1649 (DOI:10.1039/d2me00168c).
- Design of discotic liquid crystal enabling complete switching between and memory of two alignment states over a large area
Y. Shoji, M. Kobayashi, A. Kosaka, R. Haruki, R. Kumai, S. Adachi, T. Kajitani, T. Fukushima
Chem. Sci. 2022, 13, 9891–9901 (DOI:10.1039/D2SC03677K).
- Ultrafast Singlet Fission and Efficient Carrier Transport in a Lamellar Assembly of Bis[(trialkoxyphenyl)ethynyl]pentacene
H. Sakai, K. Yoshino, Y. Shoji, T. Kajitani, J. Pu, T. Fukushima, T. Takenobu, N. V. Tkachenko, T. Hasobe
J. Phys. Chem. C 2022, 126, 9396–9406 (DOI:10.1021/acs.jpcc.2c00864).
- Dielectric response of 1,1-difluorosumanene caused by an in-plane motion
M. Li, J. Y. Wu, K. Sambe, Y. Yakiyama, T. Akutagawa, T. Kajitani, T. Fukushima, K. Matsuda, H. Sakurai
Mater. Chem. Front. 2022, 6, 1752–1758 (DOI: 10.1039/D2QM00134A).
- Chalcogen Bond versus Halogen Bond: Changing Contributions in Determining the Crystal Packing of Dihalobenzochalcogenadiazoles
Y. Ishigaki, K. Shimomura, K. Asai, T. Shimajiri, T. Akutagawa, T. Fukushima, T. Suzuki
Bull. Chem. Soc. Jpn. 2022, 95, 522–531 (DOI: 10.1246/bcsj.20220008).
- Capturing the Trajectory of Metal-Ion-Cluster Formation: Stepwise Accumulation of Zn(II) Ions in a Robust Coordination Space Formed by a Rigid Tridentate Carboxylate Ligand
M. Kato, T. Fukui, H. Sato, Y. Shoji, T. Fukushima
Inorg. Chem. 2022, 61, 3649–3654 (DOI: 10.1021/acs.inorgchem.1c03758).
Selected as Supplementary Cover
- Photoactuating Artificial Muscles of Motor Amphiphiles as an
Extracellular Matrix Mimetic Scaffold for Mesenchymal Stem Cells
S. Chen, L. Yang, F. King-Chi Leung, T. Kajitani, M. C. A. Stuart, T. Fukushima, P. v. Rijn, B. L. Feringa
J. Am. Chem. Soc, 2022, in press, (DOI: 10.1021/jacs.1c12318).
- Understanding the evolution of the Raman spectra of molecularly p-doped poly(3-hexylthiophene-2,5-diyl): signatures of polarons and bipolarons
A. E. Mansour, A. Valencia, D. Lungwitz, B. Wegner, N. Tanaka, Y. Shoji, T. Fukushima, A. Opitz, C. Cocchi, N. Koch
Phys. Chem. Chem. Phys. 2022, 24, 3109–3118 (DOI: 10.1039/D1CP04985B).
- Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond
Y. Shoji, N. Tanaka, Y. Ikabata, H. Sakai, T. Hasobe, N. Koch, H. Nakai, T. Fukushima
Angew. Chem. Int. Ed. 2022, 61, e202113549 (DOI: 10.1002/anie.202113549).
Selected as "Very Important Paper (VIP)" and Front Cover
- Introduction of Triptycene with a Particular Substitution Pattern into Polymer Chains Can Dramatically Improve the Structural and Rheological Properties
F. Ishiwari, G. Okabe, T. Kajitani, T. Fukushima
ACS Macro Lett. 2021, 10, 1529-1534 (DOI: 10.1021/acsmacrolett.1c00660).
- Visualization of Thermal Transport Properties of Self-Assembled Monolayers on Au(111) by Contact and Noncontact Scanning Thermal Microscopy
S. Fujii, Y. Shoji, T. Fukushima, T. Nishino
J. Am. Chem. Soc. 2021, 143, 18777–18783 (DOI: 10.1021/jacs.1c09757).
- Structure-Preserving Solid-State Thermal Huisgen Cycloaddition Polymerization of a Self-Assembled Triptycene-Based AB3-Type Monomer
F. Ishiwari, S. Kawahara, T. Kajitani, T. Fukushima
Chem. Lett. 2021, 50, 2006–2010 (DOI: 10.1246/cl.210476).
- A single-molecule conductance study on the rotational isomers of a hexaarylbenzene derivative carrying dipolar rotating units
T. Miyazaki, Y. Shoji, S. Fujii, T. Fukushima
Jpn. J. Appl. Phys. 2021, 60, 108002 (DOI: 10.35848/1347-4065/ac26a9).
- An Air- and Water-Stable B4N4-Heteropentalene Serving as a Host Material for a Phosphorescent OLED
J. Kashida, Y. Shoji, Y. Ikabata, H. Taka, H. Sakai, T. Hasobe, H. Nakai, T. Fukushima
Angew. Chem. Int. Ed. 2021, 60, 23812–23818 (DOI: 10.1002/anie.202110050).
- Cyano-Substituted Triptycene-Based Monolayers on Au(111): Tripodal Adsorption, Dipole Engineering, and Charge Transfer
S. Das, A. Asyuda, Y. Shoji, A. Kosaka, T. Fukushima, M. Zharnikov
J. Phys. Chem. C 2021, 125, 18968–18978 (DOI: 10.1021/acs.jpcc.1c05618).
- Mobility enhancement of DNTT and BTBT derivative organic thin-film transistors by triptycene molecule modification
M. Sugiyama, S. Jancke, T. Uemura, M. Kondo, Y. Inoue, N. Namba, T. Araki, T. Fukushima, T. Sekitani
Organic Electronics 2021, 96, 106219 (DOI: 10.1016/j.orgel.2021.106219).
- Porous Honeycomb Self-Assembled Monolayers: Tripodal Adsorption and Hidden Chirality of Carboxylate Anchored Triptycenes on Ag
S. Das, G. Nascimbeni, R. Ortiz de la Morena, F. Ishiwari, Y. Shoji, T. Fukushima, M. Buck, E. Zojer, and M. Zharnikov
ACS Nano 2021, 15, 11168–11179 (DOI:10.1021/acsnano.1c03626).
- An Element-Substituted Cyclobutadiene Exhibiting High-Energy Blue Phosphorescence
Y. Shoji, Y. Ikabata, I. Ryzhii, R. Ayub, O. El Bakouri, T. Sato, Q. Wang, T. Miura, B. S. B. Karunathilaka, Y. Tsuchiya, C. Adachi, H. Ottosson, H. Nakai, T. Ikoma, T. Fukushima
Angew. Chem. Int. Ed. 2021,60, 21817–21823 (DOI: 10.1002/anie.202106490).
Selected as "Very Important Paper (VIP)" and Inside Cover
- Manipulation of Dual Fluorescence Behavior in Aggregation-induced Emission Enhancement of a Tetraphenylethene-appended Polymer by Optical Tweezers
S.-F. Wang, B.-W. Chen, A. Itagaki, F. Ishiwari, T. Fukushima, H. Masuhara, T. Sugiyama
J. Mater. Chem. C 2021, 9, 7545–7554 (DOI: 10.1039/D1TC01631H).
- Thermal and Gas Adsorption Properties of Tröger's base/Diazacyclooctane Hybrid Ladder Polymers
K. Inoue, R. Selyanchyn, S. Fujikawa, F. Ishiwari, T. Fukushima
ChemNanoMat 2021, 7, 824–830 (DOI: 10.1002/cnma.202100151).
- Observation of Borane–Olefin Proximity Interaction Governing the Structure and Reactivity of Boron‐Containing Macrocycles Y. Murata, K. Matsunagi, J. Kashida, Y. Shoji, C. Özen, S. Maeda, T. Fukushima
Angew. Chem. Int. Ed. 2021, 60, 14630–14635 (DOI: 10.1002/anie.202103512).
- Perchlorinated Triptycene Tribenzoquinone Y. Shoji, S. Yamamoto, T. Fukushima
Chem. Lett. 2021, 50, 1240–1243 (DOI:10.1246/cl.210219).
- End-functionalization of dithiarubicene: Modulation of optoelectronic properties by metal-catalyzed coupling reactions and device application K. Tsukamoto, K. Takagi, K. Yamamoto, Y. Ie, T. Fukushima
J. Mater. Chem. C 2021, 9, 5920–5929 (DOI:10.1039/D1TC01169C).
- Two‐step Conformational Control of a Dibenzo Diazacyclooctane Derivative by Stepwise Protonation F. Ishiwari, S. Miyake, K. Inoue, K. Hirose, T. Fukushima, A. Saeki
Asian J. Org. Chem. 2021, 10, 1–6 (DOI:10.1002/ajoc.202100154).
- Chalcogen Bond versus Weak Hydrogen Bond: Changing Contributions in Determining the Crystal Packing of [1,2,5]-Chalcogenadiazole-Fused Tetracyanonaphthoquinodimethanes Y. Ishigaki, K. Asai, T. Shimajiri, T. Akutagawa, T. Fukushima, T. Suzuki
Org. Mater. 2021, 3, 90–96 (DOI: 10.1055/s-0041-1725046).
- Changing the structural and physical properties of 3-arm star poly(δ-valerolactone)s by a branch-point design H. Ogiwara, F. Ishiwari, T. Kimura, Y. Yamashita, T. Kajitani, A. Sugimoto, M. Tokita, M. Takata, T. Fukushima
Chem. Commun. 2021, 57, 3901–3904 (DOI: 10.1039/D1CC01092A).
- Thermal transport properties of an oriented thin film of a paraffinic tripodal triptycene T. Imaizumi, R. Takehara, Y. Yamashita, T. Yagi, F. Ishiwari, Y. Shoji, X. Wang, Y. Murakami, T. Nishino, T. Fukushima
Jpn. J. Appl. Phys. 2021, 60, 038002 (DOI: 10.35848/1347-4065/abe340).
- Highly Sensitive Humidity Sensor Based on Aggregation-induced Emission Luminogen-Appended Hygroscopic Polymer Microresonator A. Qiagedeer, H. Yamagishi, M. Sakamoto, H. Hasebe, F. Ishiwari, T. Fukushima, Y. Yamamoto
Mater. Chem. Front. 2021, 5, 799–803 (DOI: 10.1039/D0QM00722F).
- Room-Temperature Pentacene Fluids: Oligoethylene Glycol Substituent-Controlled Morphologies and Singlet Fission K. Yoshino, H. Sakai, Y. Shoji, T. Kajitani, H. Anetai, T. Akutagawa, T. Fukushima, N. V. Tkachenko, T. Hasobe
J. Phys. Chem. B 2020, 124, 52, 11910–11918 (DOI: 10.1021/acs.jpcb.0c09754).
- Selective Synthesis of Diazacyclooctane -Containing Flexible Ladder Polymers with Symmetrically or Unsymmetrically Substituted Side Chains
K. Inoue, F. Ishiwari, T. Fukushima
Polym. Chem. 2020, 11, 3690–3694 (DOI: 10.1039/D0PY00603C).
- Spatiotemporal Dynamics of Aggregation-Induced Emission Enhancement Controlled by Optical Manipulation
S-F. Wang,J.-R. Lin, F. Ishiwari, T. Fukushima, H. Masuhara, and T. Sugiyama
Angew. Chem. 2020, 59, 7063–7068 (DOI: 10.1002/anie.201916240).
- Switching of the Conformational Flexibility of a Diazacyclooctane-Containing Ladder Polymer by Coordination and Elimination of a Lewis Acid
F. Ishiwari, M. Ofuchi, K. Inoue, Y. Sei, T. Fukushima
Polym. Chem. 2020, 11, 236–240 ( DOI: 10.1039/C9PY01104H).
Invited as"Polymer Chemistry Emerging Investigators 2020"
Selected as "Back Cover"
- Electric-Field-Controllable Conductance Switching of an Overcrowded Ethylene Self-Assembled Monolayer
S. Fujii, M. Koike, T. Nishino, Y. Shoji, T. Suzuki, T. Fukushima, M. Kiguchi
J. Am. Chem. Soc. 2019, 141, 46, 18544–18550 ( DOI: 10.1021/jacs.9b09233).
- Dual‐Controlled Macroscopic Motions in A Supramolecular Hierarchical Assembly of Motor Amphiphiles
F. K.-C. Leung, M. C. A. Stuart, T. Kajitani, T. Fukushima, B. L. Feringa
Angew. Chem. Int. Ed. 2019, 58, 10985–10989 (DOI: 10.1002/anie.201905445).
- Chiral Crystal-Lke Droplets Displaying Unidirectional Rotational Sliding
T. Kajitani, K. Motokawa, A. Kosaka, Y. Shoji, R. Haruki, D. Hashizume, T. Hikima, M. Takata, K. Yazawa, K. Morishima, M. Shibayama, T. Fukushima
Nature Mater. 2019, 18, 266–272 (DOI: 10.1038/s41563-018-0270-7).
Highlighted in Chemistry World(2019. 1. 22)
- First-Principles Study of the Adsorption Behavior of Triptycene Molecular Tripods on Au(111): Site-Selectivity and Unambiguous Molecular Orientation
T. Tada, F. Ishiwari, Y. Shoji, T. Fukushima
J. Phys. Chem. C 2019, 123, 4401–4406 (DOI: 10.1021/acs.jpcc.9b00869).
- Synthesis and Reactivity of Cyclic Borane‐Amidine Conjugated Molecules Formed by Direct 1,2‐Carboboration of Carbodiimides with 9‐Borafluorenes
J. Kashida, Y. Shoji, T. Fukushima
Chem. Asian J. 2019, 14, 1879–1885 (DOI: 10.1002/asia.201900047).
Highlighted in Chemistry Views(2019. 3. 25)
- A Versatile Scaffold for Facile Synthesis of Fluorescent Cyano- Substituted Stilbenes
S. Hayashi, M. Sakamoto b, F. Ishiwari b, T. Fukushima b, S. Yamamoto a, T. Koizumi
Tetrahedron 2019, 75, 1079–1084, (DOI: 10.1016/j.tet.2019.01.012).
- Heat-Triggered Crystallization of Liquid Crystalline Macrocycles Allowing for Conductance Switching through Hysteretic Thermal Phase Transitions
T. Muraoka, T. Shima, T. Kajitani, N. Hoshino, E. Morvan, A. Grélard, E. J. Dufourc, T. Fukushima, T. Akutagawa, K. Nabeya, and K. Kiinbara
Chem. Asian J. , 2019, 14, 141–148 (DOI: 10.1002/asia.201801372).
- Supramolecular Packing and Macroscopic Alignment Controls Actuation Speed in Macroscopic Strings of Molecular Motor Amphiphiles
F. K.-C. Leung, T. van den Enk, T. Kajitani, J. Chen, M. C. A. Stuart, J. Kuipers, T. Fukushima, B. L. Feringa
J. Am. Chem. Soc. 2018, 140, pp 17724–17733 (DOI: 10.1021/jacs.8b10778).
- A few-layer molecular film on polymer substrates to enhance the performance of organic devices
T. Yokota, T. Kajitani, R. Shidachi, T. Tokuhara, M. Kaltenbrunner, Y. Shoji, F. Ishiwari, T. Sekitani, T. Fukushima, T. Someya
Nature Nanotech. 2018, 13, 139–144 (doi:10.1038/s41565-017-0018-6).
- Artificial muscle-like function from hierarchical supramolecular assembly of photoresponsive molecular motors
J. Chen, F. K.-C. Leung, M. C. A. Stuart, T. Kajitani, T. Fukushima, E. van der Giessen, B. L. Feringa
Nature Chem. 2018, 10, 132–138 (DOI:10.1038/nchem.2887).
Highlighted in Chemical Engineering News
- Unveiling a new aspect of simple arylboronic esters: long-lived room-temperature phosphorescence from heavy-atom-free molecules
Y. Shoji, Y. Ikabata, Q. Wang, D. Nemoto, A. Sakamoto, N. Tanaka, J. Seino, H. Nakai, T. Fukushima
J. Am. Chem. Soc. 2017, 139, 2728–2733 (DOI: 10.1021/jacs.6b11984).
- A design principle of polymers processable into 2D homeotropic order
Z. Chen, Y.-T. Chan, D. Miyajima, T. Kajitani, A. Kosaka, T. Fukushima, J. M. Lobez, T. Aida
Nature Commun. 2016, 7, 13640 (doi:10.1038/ncomms13640).
- Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
Y. Shoji, N. Tanaka, S. Muranaka, N. Shigeno, H. Sugiyama, K. Takenouchi, F. Hajjaj and T. Fukushima
Nature Commun.2016, 7, 12704 (doi: 10.1038/ncomms12704). OPEN ACCESS
- Rational synthesis of organic thin films with exceptional long-range structural integrity
N. Seiki, Y. Shoji, T. Kajitani, F. Ishiwari, A. Kosaka, T. Hikima, M. Takata, T. Someya, T. Fukushima
Science 2015, 348,1122–1126 (DOI: 10.1126/science.aab1391).
- Supramolecular Linear Heterojunction Composed of Graphite-Like Semiconducting Nanotubular Segments
W. Zhang, W. Jin, T. Fukushima, A. Saeki, S. Seki, T. Aida
Science 2011, 334, 340–343. (DOI: 10.1126/science.1210369)
- Redox-Responsive Molecular Helices with Highly Condensed π-Clouds
E. Ohta, H. Sato, S. Ando, A. Kosaka, T. Fukushima, D. Hashizume, M. Yamasaki, K. Hasegawa, A. Muraoka, H. Ushiyama, K. Yamashita, T. Aida
Nature Chem. 2011, 3, 68–73 (DOI:10.1038/nchem.900)
- Large-Area Three-Dimensional Molecular Ordering of a Polymer Brush by One-Step Processing
N. Hosono, T. Kajitani, T. Fukushima, K. Ito, S. Sasaki, M. Takata, T. Aida
Science 2010, 330, 808–811 (DOI: 10.1126/science.1195302)