福元　研究業績

原著論文

2012 2011 2010 2009年以前

2011

  • π-Conjugated Polymers Consisting of 9,10-Dihydrophenanthrene Units
    Yamamoto, T; Tokimitsu, R.; Asao, T.; Iijima, T.; Fukumoto, H.; Koizumi, T.; Fukuda, T.; Ushijima, H.
    Macromol. Chem. Phys. 2011, 212, 2406─2416. (DOI:10.1002/macp.201100310)
  • Preparation of Head-to-tail π-Conjugated Poly(thiophene-pyridine) and Poly(pyrimidine) by Organometallic Polycondensation
    Fukumoto, H.; Fujiwara, Y.; Yamamoto, T.
    Chem. Lett. 2011, 40, 992─994. (DOI:10.1246/cl.2011.992)
  • Bithiophene-Bithiazole Alternating Copolymers with Thiophene Side Chains: Synthesis by Orgaonmetallic Polycondensation and Chemical Properties of the Copolymers
    Yamamoto, T; Otsuka, S.-i.; Fukumoto, H.; Sakai, Y.; Aramaki, S.; Fukuda, T.; Emoto, A.; Ushijima, H.
    J. Polym. Sci. Part A: Polym. Chem. 2011, 49, 1508─1512. (DOI:10.1002/pola.24557)

2010

  • π-Conjugated Poly(aryleneethynylene)s Consisting of Salophen and Ni-Salophen Units in the π-Conjugated Main Chain: Preparation and Chemical Properties
    Fukumoto, H.; Yamane, K.; Kase, Y.; Yamamoto, T.
    Macromolecules 2010, 43, 10366─10375. (DOI:10.1021/ma101800f)
  • Molecular Beam Deposition of Nanoscale Ionic Liquids in Ultrahigh Vacuum
    Maruyama, S.; Takeyama, Y.; Taniguchi, H.; Fukumoto, H.; Itoh, M.; Kumigashira, H.; Oshima, M.; Yamamoto, T.; Matsumoto, Y.
    ACS nano 2010, 4, 5946─5952. (DOI:10.1021/nn101036v)
  • Synthesis of New Thiophene-Based π-Conjugated Organic Compounds and Polymer
    Usui, M.; Fukumoto, H.; Yamamoto, T.
    Bull. Chem. Soc. Jpn. 2010, 83, 1397─1399. (DOI:10.1246/bcsj.20100129)
  • π-Conjugated Polymers Consisting of Isothianaphthene and Dialkoxy-p-phenylene Units: Synthesis, Self-Assembly, and Chemical and Physical Properties
    Yamamoto, T.; Usui, M.; Ootsuka, H.; Iijima, T.; Fukumoto, H.; Sakai, Y.; Aramaki, S.; Yamamoto, H. M.; Yagi, T.; Tajima, H.; Okada, T.; Fukuda, T.; Emoto, A.; Ushijima, H.; Hasegawa, M.; Ohtsu H.
    Macromol. Chem. Phys. 2010, 211, 2138─2147. (DOI:10.1002/macp.201000246)
  • Ionic Polymers and Oligomers with Expanded π-Conjugation System Derived from Through-space Interaction in Piperazinium Ring
    Yamaguchi, I; Kado, A; Fukuda, T.; Fukumoto, H.; Yamamoto, T.; Sato, M.
    Eur. Polym. J. 2010, 46, 1119─1130. (DOI:10.1002/pi.2913)

2009年以前

  • Time-resolved Photoluminescence Study and Microcapillary Laser of Blue-emissive π-Conjugated Polymers Based on 9,10-Dihydrophenanthrene Unit
    Masuyama, K.; Yamasaki, N.; Fujii, A.; Asao, T.; Fukumoto, H.; Yamamoto, T.; Hidayat, R.; Ozaki, M.
    Jpn. J. Appl. Phys. 2009, 48, (8, Pt. 1), 082404/1─082404/3.
  • Highly Coplanar Polythiophenes with -C(≡)CR Side Chains: Self-assembly, Linear and Nonlinear Optical Properties, and Piezochromism
    Yamamoto, T.; Sato, T.; Iijima, T.; Abe, M.; Fukumoto, H.; Koizumi, T.; Usui, M.; Nakamura, Y.;  Yagi, T.; Tajima, H.; Okada, T.; Sasaki, S.; Kishida, H.; Nakamura, A.; Fukuda, T.; Emoto, A.; Ushijima, H.; Kurosaki, C.; Hirota, H.
    Bull. Chem. Soc. Jpn. 2009, 82, 896─909.
  • Preparation of Head-to-head Type Substituted Polyacetylenes by Organometallic Polycondensation
    Yamamoto, T.; Ohya, K.; Kobayashi, K.; Okamoto, K.; Koie, S.; Fukumoto, H.; Koizumi, T.; Yamaguchi, I.
    Macromolecules 2009, 42, 3207─3210.
  • π-Conjugated Poly(pyrimido[5,4-d]pyrimidine-2,6-diyl)s with Two Different Alkylamino Groups: Synthesis, Chemical Properties, and Structure
    Fukumoto, H.; Takatsuki, S.; Lee, B.-L.; Yamamoto, T
    Synth. Met. 2009, 159, 900─904.
  • Dibromides of BOC-Protected 1-Aminopyrrole and 4-Amino-1,2,4-triazole: Synthesis, X-Ray Molecular Structure, and NMR Behavior
    Yamamoto, T; Tanaka, G.; Fukumoto, H.; Koizumi, T.
    Heterocycles 2009, 78, 117─125.
  • Optical Properties and Microcapillary Laser of Blue-Emissive π-Conjugated Polymers Based on 9,10-Dihydrophenanthrene Unit
    Masuyama, K.; Fujii, A.; Nakao, T.; Asao, T.; Fukumoto, H.; Yamamoto, T.; Sakai, J.; Hidayat, R.; Ozaki, M.
    Jpn. J. Appl. Phys. 2008, 47, (6, Pt. 1), 4724─4727.
  • Electrochemical and Chemical Doping Behavior of Bithiophene-bithiazole Copolymer
    Otsuka, S.-i.; Fukumoto, H.; Yamamoto, T.
    Bull. Chem. Soc. Jpn. 2008, 81, 536─538.
  • Preparation and Chemical Properties of Soluble p-Conjugated Poly(aryleneethynylene) Consisting of Azabenzothiadiazole as the Electron-Accepting Unit
    Fukumoto, H.; Yamamoto, T.
    J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 2975─2982.
  • Chemical and Electrochemical Oxidation of Thiophene-Pyridine and Thiophene-Pyrimidine Co-Oligomers in Solutions
    Kumagai, A.; Fukumoto, H.; Yamamoto, T.
    J. Phys. Chem. B, 2007, 111, 8020─8026.
  • π-Conjugated a,w-Diphenylpolyene Complexes of RuClCp* Fragment(s) in eta4-s-cis Conformation
    Fukumoto, H.; Mashima, K.
    Eur. J. Inorg. Chem. 2006, 5006─5011.
  • Alternating Copolymer of Bithiophene and Dialkylbithiazole and Its Tendency to Align on the Surfaces
    Yamamoto, T.; Otsuka, S.-i.; Namekawa, K.; Fukumoto, H.; Yamaguchi, I.; Fukuda, T.; Asakawa, N.; Yamanobe, T.; Shiono, T.; Cai, Z.
    Polymer 2006, 47, 6038─6041.
  • Molecular Alignments Studied by X-ray Diffraction Analysis and Optical Properties of Vacuum-Deposited Thin Films of Thiophene-pyridine co-Oligomers
    Kumagai, A.; Fujiwara, Y.; Fukumoto, H.; Sasaki, S.; Koinuma, H.; Yamamoto, T.
    Jpn. J. Appl. Phys. 2006, 45, L598─L601.
  • Synthesis and Basic Optical Properties of New π-Conjugated Thiophene-pyridine co-Oligomers
    Fukumoto, H.; Kumagai, A.; Fujiwara, Y.; Koinuma, H.; Yamamoto, T.
     Heterocycles 2006, 68, 1349─1357.
  • New Heteroaromatic Polymers Consisting of Alkyl- and Amino-1,3,5-triazine Units. Their Basic Optical Properties and n-Type Time-of-flight Drift Mobility
    Yamamoto, T.; Watanabe, S.; Fukumoto, H.; Sato, M.; Tanaka, T.
    Macromol. Rapid Commun. 2006, 27, 317─321.
  • Luminescent Palladium Complexes Containing Thioamide-based SCS Pincer Ligands
    Akaiwa, M.; Kanbara, T.; Fukumoto, H.; Yamamoto, T.
    J. Organomet. Chem. 2005, 690, 4192─4196.
  • Synthesis of 3-Alkynyl-2,5-dibromothiophene and 3,3'-Dialkynyl-5,5'-dibromo-2,2'-bithiophene as the Starting Compounds for p-Conjugated Polymer
    Sato, T.; Kokubo, H.; Fukumoto, H.; Yamamoto, T.
    Bull. Chem. Soc. Jap. 2005, 78, 1368─1370.
  • Unique Preferential Conformation and Movement of Ru(acac)2 Fragment(s) Coordinated in an eta4-s-trans Fashion to All Diene Unit(s) of a,w-Diphenylpolyenes
    Fukumoto, H.; Mashima, K.
    Organometallics 2005, 24, 3932─3938.
  • Regioregular Head-to-tail Poly(6-alkylpyridine-2,5-diyl)s and a New Type of Packing Structure of the Polymer in the Solid State
    Fukumoto, H.; Kimura, R.; Sasaki, S.; Kubota, K.; Yamamoto, T.
    J. Polym. Sci., Part B: Polym. Phys. 2005, 43, 215─222.
  • Synthesis of Soluble Poly(9,10-dihydrophenanthrene-2,7-diyl)s. A New Class of Luminescent Poly(p-phenylene)s with Ethylene Type Bridges
    Yamamoto, T.; Asao, T.; Fukumoto, H.
    Polymer 2004, 45, 8085─8089.
  • Chain Distortion of m-Linked Aromatic Polymers: Poly(m-phenylene) and Poly(m-pyridine)
    Kobayashi, N.; Sasaki, S.; Abe, M.; Watanabe, S.; Fukumoto, H.; Yamamoto, T.
    Macromolecules 2004, 37, 7986─7991.
  • The First Observation of 1H-NMR Spectrum of Pentacene
    Nagano, M.; Hasegawa, T.; Myoujin, N.; Yamaguchi, J.; Itaka, K.; Fukumoto, H.; Yamamoto, T.; Koinuma, H.
    Jpn. J. Appl. Phys. 2004, 43, L315─L316.
  • Alkylation of 3,8-Dibromo-1,10-phenanthroline and New π-Conjugated Polymers, Poly(2-alkyl-1,10-phenanthroline-3,8-diyl)s, Derived from the Alkylated Monomers
    Yamamoto, T.; Anzai, K.; Iijima, T.; Fukumoto, H.
    Macromolecules 2004, 37, 3064─3067.
  • Direct Alkylation and Phenylation of 3,8-Dibromo-1,10-phenanthroline with Grignard Reagents
    Anzai, K.; Fukumoto, H.; Yamamoto, T.
    Chem. Lett. 2004, 33, 252─253.
  • Poly(1,10-phenanthroline-3,8-diyl) and Its Derivatives. Preparation, Optical and Electrochemical Properties, Solid Structure, and Their Metal Complexes
    Yamamoto, T.; Saitoh, Y.; Anzai, K.; Fukumoto, H.; Yasuda, T.; Fujiwara, Y.; Choi, B.-K.; Kubota, K.; Miyamae, T.
    Macromolecules 2003, 36, 6722─6729.
  • p-Doping Behavior of Water-soluble π-Conjugated Poly[3-(3'-sulfopropyl)thiophene]: Kinetic and Spectroscopic Studies
    Yamamoto, T.; Sakamaki, M.; Fukumoto, H.
    Synth. Met. 2003, 139, 169─173.
  • Preparation of a New Poly(p-phenylene) Type Polymer, Poly(pyrazine-2,5-diyl), with a Coplanar Structure
    Yamamoto, T.; Fujiwara, Y.; Fukumoto, H.; Nakamura, Y.; Koshihara, S.; Ishikawa, T.
    Polymer 2003, 44, 4487─4490.
  • Preparation of Soluble π-Conjugated Poly(5,6-dialkoxy-1,10-phenanthroline-3,8-diyl)s. Their Stacking Behavior and Function as a π-Conjugated Polymer Ligand
    Yamamoto, T.; Anzai, K.; Fukumoto, H.
    Chem. Lett. 2002, 774─775.
  • Synthesis and Properties of Transition Metal Complexes Assembled by Coordination to Rigid π-Conjugated Aryleneethynylene Ligands
    Fukumoto, H.; Yamamoto, T.
    Mol. Cryst. Liq. Cryst. 2002, 379, 437─442.
  • Preparation and Properties of Poly[(2-alkyl benzimidazole)-alt-thiophene]s with Long Alkyl Side Chains
    Nurulla, I.; Morikita, T.; Fukumoto, H.; Yamamoto, T.
    Macromol. Chem. Phys. 2001, 202, 2335─2340.
  • Preparation and Characterization of Regioregular Head-to-tail π-Conjugated Poly(pyridine-2,5-diyl)s
    Yamamoto, T.; Nakamura, T.; Fukumoto, H.; Kubota, K.
    Chem. Lett. 2001, 502─503.
  • Synthesis and Characterization of New π-Conjugated Polymer Complexes with Transition Metal Fragments
    Fukumoto, H.; Hayashida, N.; Maruyama, T; Yamamoto, T.
    Mol. Cryst. Liq. Cryst. 2000, 342, 237─240.
  • Energy Gap Dependence of the S2 → S1 Internal Conversion of alpha,omega-Diphenylpolyenes (n = 3-8) in Solution Phase
    Hirata, Y.; Mashima, K.; Fukumoto, H.; Tani, K.; Okada, T.
    Chem. Phys. Lett. 1999, 308, 176─180.
  • Polymerization of Acrylonitrile Catalyzed by Thiolate Complexes of Divalent and Trivalent Lanthanoids
    Nakayama, Y.; Fukumoto, H.; Shibahara, T.; Nakamura, A.; Mashima, K.
    Polym. Internat. 1999, 48, 502─504.
  • Cationic Monocyclooctatetraenyl-lanthanoid Complexes Derived from Metallic Lanthanoid: Crystal Structures of [Sm(eta-C8H8)(hmpa)3]I and [Sm(eta-C8H8)(hmpa)3][Sm(eta-C8H8)2] (HMPA = Hexamethylphosphoric triamide)
    Mashima, K.; Fukumoto, H.; Nakayama, Y.; Tani, K.; Nakamura, A.
    Polyhedron 1998, 17, 1065─1071.
  • 1,8-Diphenylocta-1,3,5,7-tetraene Complexes of Ruthenium(II): Crystal Structures of [µ-(s-cis-1,2,3,4-h:s-cis-5,6,7,8-eta-PhCH=CHCH=CHCH=CHCH=CHPh)(RuClCp)2] and [µ-(s-trans-1,2,3,4-h:s-trans-5,6,7,8-eta-PhCH=CHCH=CHCH=CHCH=CHPh){Ru(acac)2}2]
    Mashima, K.; Fukumoto, H.; Tani, K.; Haga, M.; Nakamura, A.
    Organometallics 1998, 17, 410─414.
  • Ligand Exchange Reactions of a 1,3-Butadiene Complex of Magnesium
    Mashima, K.; Matsuo, Y.; Fukumoto, H.; Tani, K.; Yasuda, H.; Nakamura, A.
    J. Organomet. Chem. 1997, 545-546, 549─552.
  • Thermochromism and Dynamics of Organometallic Conjugated Systems: Zirconocene Complex of 1,4-Diphenyl-1,3-butadiene
    Takeda, S.; Fukumoto, H.; Mashima, K.; Maruta, G.; Yamaguchi, K.; Nakamura, A.
    J. Phys. Chem. B 1997, 101, 278─284.
  • Syndiospecific Polymerization of Methyl Methacrylate Catalyzed by Lanthanoid Thiolate Complexes Bearing a Hexamethylphosphoric Triamide Ligand
    Nakayama, Y.; Shibahara, T.; Fukumoto, H.; Nakamura, A.; Mashima, K.
    Macromolecules 1996, 29, 8014─8016.
  • Synthesis of Arenethiolate Complexes of Divalent and Trivalent Lanthanides from Metallic Lanthanides and Diaryl Disulfides: Crystal Structures of [{Yb(hmpa)3}2(µ-SPh)3][SPh] and Ln(SPh)3(hmpa)3 (Ln = Sm, Yb; hmpa = Hexamethylphosphoric Triamide)
    Mashima, K.; Nakayama, Y.; Shibahara, T.; Fukumoto, H.; Nakamura, A.
    Inorg. Chem. 1996, 35, 93─99.
  • Formation of Lanthanoid(II) and Lanthanoid(III) Thiolate Complexes Derived from Metals and Organic Disulfides: Crystal Structures of [{Ln(SAr)(µ-SAr)(thf)3}2] (Ln = Sm, Eu), [Sm(SAr)3(py)2(thf)] and [Yb(SAr)3(py)3] (Ar = 2,4,6-triisopropylphenyl; py = pyridine)
    Mashima, K.; Nakayama, Y.; Fukumoto, H.; Kanehisa, N.; Kai, Y.; Nakamura, A.
    J. Chem. Soc., Chem Commun. 1994, 21, 2523─2524.

総説

  • Metal Complexes of π-Conjugated Polymers
    Yamamoto, T.; Fukumoto, H.; Koizumi, T.
    J. Inorg. Organomet. Polym. 2009, 19, 3─11.
  • Combinatorial Physical Vapor Deposition of π-Conjugated Organic Thin Film Libraries
    Fukumoto, H.; Muramatsu, Y.; Yamamoto, T.; Yamaguchi, J.; Itaka, K.; Koinuma, H.
    Macromol. Rapid Commun. 2004, 25, 196─203.

著書

  • π共役高分子
    福元博基
    有機半導体デバイス－基礎から最先端材料・デバイスまで－
    オーム社、98─102 (2010).
  • Metal Complexes of π-Conjugated Polymers and Related Polymers
    Yamamoto, T.; Fukumoto, H.
    Macromolecules Containing Metal and Metal-Like Elements, Volume 5 (Metal-Coordination Polymers), Wiley-interscience, 285─296 (2005).
  • π共役高分子合成用触媒
    福元博基、神原貴樹、山本隆一
    触媒活用大事典、工業調査会、674─678 (2004).
  • 導電性高分子材料の合成
    山本隆一、福元博基
    導電性高分子材料の開発と応用、技術情報協会、25─30 (2001).
  • 芳香族π共役高分子の光・電子機能
    山本隆一、福元博基
    有機半導体デバイス－基礎から最先端材料・デバイスまで－
    次世代高分子設計、アイピーシー、205─220 (2000).
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東京工業大学
科学技術創成研究院
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