FUKUSHIMA GROUP - 東京工業大学科学技術創成研究院化学生命科学研究所　物質理工学院応用科学系

庄子 研究業績

Papers

• Insights into Chemical Bonding Modes and Heat Transport at the Molecular Level
  S. Fujii, Y. Shoji, Y. Masuda, T. Fukushima, T. Nishino
  J. Phys. Chem. Lett. 2024, 15, 11189–11193 (DOI:10.1021/acs.jpclett.4c02325).
  

• Supramolecular scaffold-directed two-dimensional assembly of pentacene into a configuration to facilitate singlet fission
  M. Fukumitsu, T. Fukui, Y. Shoji, T. Kajitani, R. Khan, N. V. Tkachenko, H. Sakai, T. Hasobe, T. Fukushima
  Sci. Adv. 2024, 10, eadn7763 (DOI:10.1126/sciadv.adn7763).
  
originally posted on ChemRxiv (DOI:10.26434/chemrxiv-2024-x9rjg-v2).

• Fluorescence Detection of Tetraphenylporphyrin Isolated on the Au(111) Electrode Enabled by Tripodal Molecules
  Y. Kobayashi, Y. Yokota, Y. Shoji, S. Sajisha, C. J. Martin, J. Takeya, T. Fukushima, Y. Kim
  J. Phys. Chem. C 2024, 128, 15082–15090 (DOI:10.1021/acs.jpcc.4c04400).
  

• Peripheral Fusion of Carbon-based Aromatic Rings to B₄N₄-Heteropentalene Leading to Close π-Stacking in the Solid State
  J. Kashida, Y. Shoji, H. Taka, F. Ishiwari, A. Saeki, T. Fukushima
  Chem. Eur. J. 2024, in press (DOI:10.1002/chem.202402862).
  

• 2D hexagonal assembly of a dipolar rotor with a close interval of 0.8 nm using a triptycene-based supramolecular scaffold
  T. Ogawa, F. Ishiwari, F. Hajjaj, Y. Shoji, T. Kajitani, K. Yazawa, T. Ohkubo, T. Fukushima
  Chem. Sci. 2024, 15, 11021-11028 (DOI:10.1039/D4SC02750G).
  
originally posted on ChemRxiv (DOI:10.26434/chemrxiv-2024-ws952).

• Recent advances in structurally elaborate triptycenes, triptycene-containing polymers and assemblies: structures, functions and applications
  F. Ishiwari, Y. Shoji, C. J. Martin, T. Fukushima
  Polym. J. 2024, in press (DOI:10.1038/s41428-024-00920-x).
  

• Phosphonic acid anchored tripodal molecular films on indium tin oxide
  C. Zhang, S. Das, N. Sakurai, T. Imaizumi, S. Sanjayan, Y. Shoji, T. Fukushima, M. Zharnikov
  Phys. Chem. Chem. Phys. 2024, 26, 11360–11369 (DOI:10.1039/D4CP00892H).
  
Selected as a 2024 HOT Article

• Ferroelectricity of alkylamide-substituted triptycene derivatives
  R. Mizoue, T. Takeda, S. Dekura, M. Kato, T. Fukui, Y. Shoji, T. Fukushima, S. Yamane, Y. Suzuki, J. Kawamata, T. Akutagawa
  J. Mater. Chem. C 2024, 12, 5578–5586 (DOI:10.1039/d3tc04752k).
  

• Triple Isomerism in 3D Covalent Organic Frameworks
  X. Wang, Y.i Wada, T. Shimada, A. Kosaka, K. Adachi, D. Hashizume, K. Yazawa, H. Uekusa, Y. Shoji, T. Fukushima, M. Kawano, Y. Murakami
  J. Am. Chem. Soc. 2024, 146, 1832–1838 (DOI:10.1021/jacs.3c13863).
  

• Appearance of Different Conductance States in Monomolecular Films of Ferrocene-Decorated Triptycene-Based Tripods
  Y. Liu, S. Sanjayan, Y. Shoji, T. Fukushima, M. Zharnikov
  J. Phys. Chem. C 2023, 127, 24458–24466 (DOI:10.1021/acs.jpcc.3c06634).
  

• Skeletal rearrangement of a boron-containing annulenic molecule into a macrocycle bridged by an electronically stabilized boron cation
  Y. Murata, C. Özen, S. Maeda, T. Fukushima, Y. Shoji
  Chem. Commun. 2023, 59, 13635–13638 (DOI:10.1039/D3CC04830F).
  

• Insights into Thermal Transport through Molecular π-Stacking
  R. Takehara, N. Kubo, M. Ryu, S. Kitani, S. Imajo, Y. Shoji, H. Kawaji, J. Morikawa, T. Fukushima
  J. Am. Chem. Soc. 2023, 145, 22115–22121 (DOI:10.1021/jacs.3c07921).
  

• Collective bending motion of a two-dimensionally correlated bowl-stacked columnar liquid crystalline assembly under a shear force
  Y. Shoji, R. Komiyama, M. Kobayashi, A. Kosaka, T. Kajitani, R. Haruki, R. Kumai, S. Adachi, T. Tada, N. Karasawa, H. Nakamura, H. Sakurai, T. Fukushima
  Sci. Adv. 2023, 9, eadg8202 (DOI:10.1126/sciadv.adg820).
  

• Triptycene-Based Self-Assembled Monolayer as a Template for Successive Click Reactions
  S. Das, F. Ishiwari, Y. Shoji, T. Fukushima, M. Zharnikov
  J. Phys. Chem. C. 2023, 127, 5178–5185 (DOI:10.1021/acs.jpcc.3c00443).
  

• Synthesis and Properties of B₄N₄-Heteropentalenes Fused with Polycyclic Hydrocarbons
  J. Kashida, Y. Shoji, H. Taka, T. Fukushima
  Chem. Eur. J. 2023, 29, e202203561 (DOI:10.1002/chem.202203561).
  

• Triptycene-Based Tripodal Self-Assembled Monolayer on Indium Tin Oxide
  Saunak Das, Fumitaka Ishiwari, Yoshiaki Shoji, Takanori Fukushima, and Michael Zharnikov
  J. Phys. Chem. C.  2023, 127, 2088–2097 (DOI: 10.1021/acs.jpcc.2c08390).
  

• Single-Molecule Observation of Redox Reactions Enabled by Rigid and Isolated Tripodal Molecules
  Y. Kobayashi, Y. Yokota, R. A. Wong, M. Hong, J. Takeya, S. Osawa, F. Ishiwari, Y. Shoji, T. Harimoto, K. Sugimoto, Y. Ishigaki, T. Suzuki, T. Fukushima, Y. Kim
  J. Phys. Chem. C  2023, 127, 746–758 (DOI: 10.1021/acs.jpcc.2c07362).
  

• Design of discotic liquid crystal enabling complete switching between and memory of two alignment states over a large area
  Y. Shoji, M. Kobayashi, A. Kosaka, R. Haruki, R. Kumai, S. Adachi, T. Kajitani, T. Fukushima
  Chem. Sci. 2022, 13, 9891–9901 (DOI:10.1039/D2SC03677K).
  Highlighted in 2022 Chemical Science HOT Article Collection
  

• Ultrafast Singlet Fission and Efficient Carrier Transport in a Lamellar Assembly of Bis[(trialkoxyphenyl)ethynyl]pentacene
  H. Sakai, K. Yoshino, Y. Shoji, T. Kajitani, J. Pu, T. Fukushima, T. Takenobu, N. V. Tkachenko, T. Hasobe
  J. Phys. Chem. C 2022, 126, 9396–9406 (DOI:10.1021/acs.jpcc.2c00864).
  

• A carbon-functionality-appended diborylacetylene available for a component of organic synthesis and OLEDs
  T. Tsukada, Y. Shoji, K. Takenouchi, H. Taka, T. Fukushima
  Chem. Commun. 2022, 58, 4973–4976 (DOI: 10.1039/D2CC01159J).

• Bringing out the potential of organoboron compounds by designing the chemical bonds and spaces around boron
  Y. Shoji, J. Kashida, T. Fukushima
  Chem. Commun. 2022, 4420–4434 (DOI: 10.1039/D2CC00653G).

• Capturing the Trajectory of Metal-Ion-Cluster Formation: Stepwise Accumulation of Zn(II) Ions in a Robust Coordination Space Formed by a Rigid Tridentate Carboxylate Ligand
  M. Kato, T. Fukui, H. Sato, Y. Shoji, T. Fukushima
  Inorg. Chem. 2022, 61, 3649–3654 (DOI: 10.1021/acs.inorgchem.1c03758).
Selected as Supplementary Cover

• Understanding the evolution of the Raman spectra of molecularly p-doped poly(3-hexylthiophene-2,5-diyl): signatures of polarons and bipolarons
  A. E. Mansour, A. Valencia, D. Lungwitz, B. Wegner, N. Tanaka, Y. Shoji, T. Fukushima, A. Opitz, C. Cocchi, N. Koch
  Phys. Chem. Chem. Phys. 2022, 24,  3109–3118 (DOI: 10.1039/D1CP04985B).

• Tetraaryldiborane(4) Can Emit Dual Fluorescence Responding to the Structural Change around the B–B Bond
  Y. Shoji, N. Tanaka, Y. Ikabata, H. Sakai, T. Hasobe, N. Koch, H. Nakai, T. Fukushima
  Angew. Chem. Int. Ed. 2022, 61, e202113549 (DOI: 10.1002/anie.202113549).
Selected as "Very Important Paper (VIP)" and Front Cover

• Visualization of Thermal Transport Properties of Self-Assembled Monolayers on Au(111) by Contact and Noncontact Scanning Thermal Microscopy
  S. Fujii, Y. Shoji, T. Fukushima, T. Nishino
  J. Am. Chem. Soc. 2021, 143, 18777–18783 (DOI: 10.1021/jacs.1c09757).

• A single-molecule conductance study on the rotational isomers of a hexaarylbenzene derivative carrying dipolar rotating units
  T. Miyazaki, Y. Shoji, S. Fujii, T. Fukushima
  Jpn. J. Appl. Phys. 2021, 60, 108002 (DOI: 10.35848/1347-4065/ac26a9).

• An Air- and Water-Stable B₄N₄-Heteropentalene Serving as a Host Material for a Phosphorescent OLED
  J. Kashida, Y. Shoji, Y. Ikabata, H. Taka, H. Sakai, T. Hasobe, H. Nakai, T. Fukushima
  Angew. Chem. Int. Ed. 2021, 60, 23812–23818 (DOI: 10.1002/anie.202110050).

• Cyano-Substituted Triptycene-Based Monolayers on Au(111): Tripodal Adsorption, Dipole Engineering, and Charge Transfer
  S. Das, A. Asyuda, Y. Shoji, A. Kosaka, T. Fukushima, M. Zharnikov
  J. Phys. Chem. C 2021, 125, 18968–18978 (DOI: 10.1021/acs.jpcc.1c05618).

• Porous Honeycomb Self-Assembled Monolayers: Tripodal Adsorption and Hidden Chirality of Carboxylate Anchored Triptycenes on Ag
  S. Das, G. Nascimbeni, R. Ortiz de la Morena, F. Ishiwari, Y. Shoji, T. Fukushima, M. Buck, E. Zojer, and M. Zharnikov 
  ACS Nano 2021, 15, 11168–11179 (DOI:10.1021/acsnano.1c03626).

• An Element-Substituted Cyclobutadiene Exhibiting High-Energy Blue Phosphorescence
  Y. Shoji, Y. Ikabata, I. Ryzhii, R. Ayub, O. El Bakouri, T. Sato, Q. Wang, T. Miura, B. S. B. Karunathilaka, Y. Tsuchiya, C. Adachi, H. Ottosson, H. Nakai, T. Ikoma, T. Fukushima
  Angew. Chem. Int. Ed. 2021, 60, 21817–21823 (DOI: 10.1002/anie.202106490).
Selected as "Very Important Paper (VIP)" and Inside Cover

• Observation of Borane–Olefin Proximity Interaction Governing the Structure and Reactivity of Boron‐Containing Macrocycles
Y. Murata, K. Matsunagi, J. Kashida, Y. Shoji, C. Özen, S. Maeda, T. Fukushima
Angew. Chem. Int. Ed. 2021, 60, 14630–14635 (DOI: 10.1002/anie.202103512).

• Perchlorinated Triptycene Tribenzoquinone
Y. Shoji, S. Yamamoto, T. Fukushima
Chem. Lett. 2021, 50, 1240–1243 (DOI:10.1246/cl.210219).  

• Thermal transport properties of an oriented thin film of a paraffinic tripodal triptycene
T. Imaizumi, R. Takehara, Y. Yamashita, T. Yagi, F. Ishiwari, Y. Shoji, X. Wang, Y. Murakami, T. Nishino, T. Fukushima
Jpn. J. Appl. Phys. 2021, 60, 030802 (DOI: 10.35848/1347-4065/abe340).

• Room-Temperature Pentacene Fluids: Oligoethylene Glycol Substituent-Controlled Morphologies and Singlet Fission
K. Yoshino, H. Sakai, Y. Shoji, T. Kajitani, H. Anetai, T. Akutagawa, T. Fukushima, N. V. Tkachenko, T. Hasobe
J. Phys. Chem. B 2020, 124, 11910–11918 (DOI: 10.1021/acs.jpcb.0c09754).

• Design of a molecular memory element with an alternating circular array of dipolar rotors and rotation suppressors
  T. Miyazaki, Y. Shoji, F. Ishiwari, T. Kajitani, T. Fukushima
  Chem. Sci. 2020, 11, 8388–8393 (DOI: 10.1039/D0SC02836C).
Selected as Inside Front Cover

• An Organic Borate Salt with Superior p-Doping Capability for Organic Semiconductors
  B. Wegner, D. Lungwitz, A. E. Mansour, C. E. Tait, N. Tanaka, T. Zhai, S. Duhm, M. Forster, J. Behrends, Y. Shoji, A. Opitz, U. Scherf, E. J. W. List-Kratochvil, T. Fukushima, N. Koch 
  Adv. Sci. 2020, 2001322 (DOI: 10.1002/advs.202001322).

• Self-Assembly Growth of an Upright Molecular Precursor with a Rigid Framework
  S. Chaunchaiyakul, C. Zhang, H. Imada, E. Kazuma, F. Ishiwari, Y. Shoji, T. Fukushima, Y. Kim
  J. Phys. Chem. C 2019, 123, 31272–31278 (DOI: 10.1021/acs.jpcc.9b09948).

• Electric-Field-Controllable Conductance Switching of an Overcrowded Ethylene Self-Assembled Monolayer
  S. Fujii, M. Koike, T. Nishino, Y. Shoji, T. Suzuki, T. Fukushima, M. Kiguchi
  J. Am. Chem. Soc. 2019, 141, 18544–18550 ( DOI: 10.1021/jacs.9b09233).

• Ultralow-Noise Organic Transistors Based on Polymeric Gate Dielectrics with Self-Assembled Modifiers
  M. Kondo, T. Uemura, F. Ishiwari, T. Kajitani, Y. Shoji, M. Morita, N. Namba, Y. Inoue, Y. Noda, T. Araki, T. Fukushima, T. Sekitani
  ACS Appl. Mater. Interfaces 2019, 11, 41561–41569  (DOI: 10.1021/acsami.9b13056).

• Highly-ordered Triptycene Modifier Layer Based on Blade Coating for Ultraflexible Organic Transistors
  M. Kondo, T. Kajitani, T.Uemura, Y. Noda, F. Ishiwari, Y. Shoji, T. Araki, S. Yoshimoto, T. Fukushima, T. Sekitani
  Sci. Rep. 2019, 9, 9200  (DOI: 10.1038/s41598-019-45559-4).

• Triptycene Tripods for the Formation of Highly Uniform and Densely Packed Self-Assembled Monolayers with Controlled Molecular Orientation
  F. Ishiwari, G. Nascimbeni, E. Sauter, H. Tago, Y. Shoji, S. Fujii, M. Kiguchi, T. Tada, M. Zharnikov, E. Zojer, T. Fukushima
  J. Am. Chem. Soc. 2019, 141, 5995–6005 (DOI: 10.1021/jacs.9b00950).

• First-Principles Study of the Adsorption Behavior of Triptycene Molecular Tripods on Au(111): Site-Selectivity and Unambiguous Molecular Orientation
  T. Tada, F. Ishiwari, Y. Shoji, T. Fukushima
  J. Phys. Chem. C 2019, 123, 4401–4406 (DOI: 10.1021/acs.jpcc.9b00869).

• Synthesis and Reactivity of Cyclic Borane‐Amidine Conjugated Molecules Formed by Direct 1,2‐Carboboration of Carbodiimides with 9‐Borafluorenes
  J. Kashida, Y. Shoji, T. Fukushima
  Chem. Asian J. 2019, 14, 1879–1885 (DOI: 10.1002/asia.201900047).
Highlighted in Chemistry Views（2019. 3. 25）

• Formation of environmentally stable hole-doped graphene films with instantaneous and high-density carrier doping via a boron-based oxidant
  K. Kanahashi, N. Tanaka, Y. Shoji, M. Maruyama, I. Jeon, K. Kawahara, M. Ishihara, M. Hasegawa, H. Ohta, H. Ago, Y. Matsuo, S. Okada, T. Fukushima, T. Takenobu
  npj 2D Materials and Applications, 2019, 3, article number 7 (DOI: 10.1038/s41699-019-0090-x).

• A Theoretical Study on the Mechanism of the Oxidative Deborylation/C–C Coupling Reaction of Borepin Derivatives
  C. Ozen, Y. Shoji, T. Fukushima, S. Maeda
  J. Org. Chem. 2019, 84, 1941–1950 (DOI: 10.1021/acs.joc.8b02917).

• Chiral Crystal-Like Droplets Displaying Unidirectional Rotational Sliding
  T. Kajitani, K. Motokawa, A. Kosaka, Y. Shoji, R. Haruki, D. Hashizume, T. Hikima, M. Takata, K. Yazawa, K. Morishima, M. Shibayama, T. Fukushima
  Nature Mater. 2019, 18, 266–272 (DOI: 10.1038/s41563-018-0270-7). 
  プレスリリース「結晶にも液晶にも液体にも分類されない新物質を発見」（2019. 1. 22）
Highlighted in Chemistry World（2019. 1. 22）

• Ring shape-dependent self-sorting of pillar[n]arenes assembled on a surface
  T. Ogoshi, S. Takashima, N. Inada, H. Asakawa, T. Fukuma, Y. Shoji, T. Kajitani, T. Fukushima, T. Tada, T. Dotera, T. Kakut, T. Yamagishi
  Comms. Chem. 2018, 1:92, 1–7 (DOI: 10.1038/s42004-018-0094-z).

• Induced-fit expansion and contraction of a self-assembled nanocube finely responding to neutral and anionic guests
  Y.-Y. Zhan, T. Kojima, T. Nakamura, T. Takahashi, S. Takahashi, Y. Haketa, Y. Shoji, H. Maeda, T. Fukushima, S. Hiraoka
  Nature Commun. 2018, 9, 4530 (DOI: 10.1038/s41467-018-06874-y).

• Sensing the chirality of various organic solvents by helically arranged π-blades
  Y. Shimizu, Y. Shoji, D. Hashizume, Y. Nagata, T. Fukushima
  Chem. Commun. 2018, 54, 12314-12317 (DOI: 10.1039/C8CC06277C).
  Selected as "Back Cover"
  Highlighted in Chemistry World (Nov. 7, 2018)

• Mechanistic Study on Highly Efficient Direct 1,2‐Carboboration of Alkynes with 9‐Borafluorenes
  Y. Shoji, N. Shigeno, K. Takenouchi, M. Sugimoto, T. Fukushima
  Chem. Eur. J. 2018, 24, 13223–13230 (DOI: 10.1002/chem.201801818).

• Highly Efficient Transformation of Linear Poly(Phenylene Ethynylene)s into Zigzag-Shaped π-Conjugated Microporous Polymers through Boron-Mediated Alkyne Benzannulation
  Y. Shoji, M. Hwang, H. Sugiyama, F. Ishiwari, K. Takenouchi, R. Osuga, J. N. Kondo, S. Fujikawa, T. Fukushima
  Mater. Chem. Front. 2018, 2, 807–814 (DOI: 10.1039/C7QM00582B).

• Supramolecular scaffolds enabling the controlled assembly of functional molecular units
  F. Ishiwari, Y. Shoji, T. Fukushima 
  Chem. Sci. 2018, 9, 2028–2041 (DOI: 10.1039/C7SC04340F). OPEN ACCESS

• Chemical hole doping into large-area transition metal dichalcogenide monolayers using boron-based oxidant
H. Matsuoka, K. Kanahashi, N. Tanaka, Y. Shoji, L.-J. Li, J. Pu, H. Ito, T. Fukushima, T. Takenobu
Jpn. J. Appl. Phys. 2018, 57, 02CB15-1 to 02CB15-4 (DOI: 10.7567/JJAP.57.02CB15). 

• Single-molecule junction of an overcrowded ethylene with binary conductance states
M. Koike, S. Fujii, H. Cho, Y. Shoji, T. Nishino, T. Fukushima, M. Kiguchi
Jpn. J. Appl. Phys. 2018, 57, 03EG05-1 to 03EG05-4 (DOI: 10.7567/JJAP.57.03EG05).

• A few-layer molecular film on polymer substrates to enhance the performance of organic devices
  T. Yokota, T. Kajitani, R. Shidachi, T. Tokuhara, M. Kaltenbrunner, Y. Shoji, F. Ishiwari, T. Sekitani, T. Fukushima, T. Someya
  Nature Nanotech. 2018, 13, 139–144 (DOI: 10.1038/s41565-017-0018-6).
  プレスリリース「プラスチックに数層の分子配向膜を形成する手法の開発とその応用に成功」

• Hexathioalkyl sumanenes: An electron-donating buckybowl as a building block for supramolecular materials
Y. Shoji,  T. Kajitani,  F. Ishiwari,  Q. Ding,  H. Sato,  H. Anetai,  T. Akutagawa,  H. Sakurai, T. Fukushima (Y.S., F.I., and T.K. contributed equally)
Chem. Sci. 2017, 8, 8405–8410 (DOI: 10.1039/C7SC03860G).

• 2,3,5,6,8,9-Hexabromosumanene: Synthesis and Its Application to Suzuki-Miyaura Cross-Coupling
H. Toda, Y. Yakiyama, Y. Shoji, F. Ishiwari, T. Fukushima, H. Sakurai
Chem. Lett. 2017, 46, 1368–1371 (DOI: 10.1246/cl.170566).

• Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations
F. K.-C. Leung, F. Ishiwari, Y. Shoji, T. Nishikawa, R. Takeda, Y. Nagata, M. Suginome, Y. Uozumi, Y. M. A. Yamada, T. Fukushima
ACS Omega 2017, 2, 1930–1937 (DOI: 10.1021/acsomega.7b00200).

• Formation of an Isolable Divinylborinium Ion through Twofold 1,2-Carboboration between a Diarylborinium Ion and Diphenylacetylene
  N. Tanaka, Y. Shoji, D. Hashizume, M. Sugimoto, T. Fukushima
  Angew. Chem. Int. Ed. 2017, 56, 5312–5316 (DOI: 10.1002/anie.201701730).
  Selected as "Back Cover"

• Unveiling a new aspect of simple arylboronic esters: long-lived room-temperature phosphorescence from heavy-atom-free molecules
  Y. Shoji, Y. Ikabata, Q. Wang, D. Nemoto, A. Sakamoto, N. Tanaka, J. Seino, H. Nakai, T. Fukushima
  J. Am. Chem. Soc. 2017, 139, 2728–2733 (DOI: 10.1021/jacs.6b11984).

• Highly air- and moisture-stable hole-doped carbon nanotube films achieved by a boron-based oxidant
  K. Funahashi, N. Tanaka, Y. Shoji, N. Imazu, K. Nakayama, K. Kanahashi, H. Shirae, S. Noda, H. Ohta,T. Fukushima, and T. Takenobu
  Appl. Phys. Express 2017, 10, 035101 (DOI: 10.7567/APEX.10.035101).

• A ternary blend of a polymer, fullerene, and insulating self-assembling triptycene molecules for organic photovolatics
  M. Kumano, M. Ide, N. Seiki, Y. Shoji, T. Fukushima, A. Saeki
  J. Mater. Chem. A 2016, 4, 18490–18498 (DOI: 10.1039/C6TA07705F).

• Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules
  Y. Shoji, N. Tanaka, S. Muranaka, N. Shigeno, H. Sugiyama, K. Takenouchi, F. Hajjaj and T. Fukushima
  Nature Commun. 2016, 7, 12704 (DOI: 10.1038/ncomms12704).
  OPEN ACCESS, プレスリリース（東工大ニュース）
  Nature Communications の日本語サイト「おすすめコンテンツ」で紹介 =>  ホウ素を介するアルキン挿入とC-Cカップリングの連続反応による拡張π共役分子の合成    

• Synthesis and structural characteristics of discrete organoboron and organoaluminum hydrides incorporating bulky Eind groups
  T. Murosaki, S. Kaneda, R. Maruhashi, K. Sadamori, Y. Shoji, K. Tamao, D. Hashizume, N. Hayakawa, T. Matsuo
  Organometallics 2016, 35, 3397–3405 (DOI: 10.1021/acs.organomet.6b00633).

• Supramolecular Scaffold for Tailoring the Two-Dimensional Assembly of Functional Molecular Units into Organic Thin Films
  F. K.-C. Leung, F. Ishiwari, T. Kajitani, Y. Shoji, T. Hikima, M. Takata, A. Saeki, S. Seki, Y. M. A. Yamada, T. Fukushima
  J. Am. Chem. Soc. 2016, 138, 11727–11733 (DOI: 10.1021/jacs.6b05513).

• Scanning tunnelling microscopy analysis of octameric o-phenylenes on Au(111)
  S. Marqués-González, S. Fujii, T. Nishino, Y. Shoji, F. Ishiwari, T. Fukushima, M. Kiguchi
  RSC Advances 2016, 6, 55970–55975 (DOI: 10.1039/C6RA07173B).

• Convenient Route to Monocarba-closo-dodecaborate Anions
  N. Tanaka, Y. Shoji, T. Fukushima
  Organometallics 2016, 35, 2022–2025 (DOI: 10.1021/acs.organomet.6b00309).

• Chlorine-based inductively coupled plasma etching of GaAs wafer using tripodal paraffinic triptycene as an etching resist mask
  A. Matsutani, F. Ishiwari, Y. Shoji, T. Kajitani, T. Uehara, M. Nakagawa, T. Fukushima
  Jpn. J. Appl. Phys. 2016, 55, 06GL01-1–06GL01-3 (DOI: 10.7567/JJAP.55.06GL01).

• ¹¹B Solid-State NMR Interaction Tensors of Linear Two-Coordinate Boron: The Dimesitylborinium Cation
  A. E. Alain, Y. Shoji, T. Fukushima, D. L. Bryce
  Inorg. Chem. 2015, 54, 11889–11896 (DOI: 10.1021/acs.inorgchem.5b02161).

• Raising the metal–insulator transition temperature of VO₂ thin films by surface adsorption of organic polar molecules
  H. Shioya, Y. Shoji, N. Seiki, M. Nakano, T. Fukushima, Y. Iwasa
  Appl. Phys. Express 2015, 8, 1211011–1211014 (DOI:10.7567/APEX.8.121101).
  Selected as "Spotlights Article", 第３８回応用物理学会優秀論文賞対象論文

• The molecular and electronic structures of a thioaroyl cation formed by borinium ion-mediated C=S double bond cleavage of CS₂
  Y. Shoji, N. Tanaka, D. Hashizume, T. Fukushima
  Chem. Commun. 2015, 51, 13342–13345 (DOI: 10.1039/C5CC05645D).
  Selected as "Outside Front Cover"

• Rational synthesis of organic thin films with exceptional long-range structural integrity
  N. Seiki, Y. Shoji, T. Kajitani, F. Ishiwari, A. Kosaka, T. Hikima, M. Takata, T. Someya, T. Fukushima
  Science 2015, 348, 1122–1126 (DOI: 10.1126/science.aab1391).

• An Isolable Diborane(4) Compound with Terminal B–H Bonds: Structural Characteristics and Electronic Properties
  Y. Shoji, S. Kaneda, H. Fueno, K. Tanaka, K. Tamao, D. Hashizume, T. Matsuo
  Chem. Lett. 2014, 43, 1587–1589 (DOI:10.1246/cl.140507). Editor's Choice

• A two-coordinate boron cation featuring C–B⁺–C bonding
  Y. Shoji,  N. Tanaka,  K. Mikami,  M. Uchiyama, T. Fukushima
  Nature Chem. 2014, 6, 498–503. (DOI:10.1038/nchem.1948) =>プレスリリース（東工大ニュース）
  Highlighted in News & Views: C. Reus, M. Wagner "Boron served straight up"
            and in Chemical & Engineering News (Volume 92, Issue 20, p. 30, Concentrates)

• Synthesis and Structures of a Series of Bulky “Rind-Br” Based on a Rigid Fused-Ring s-Hydrindacene Skeleton
  T. Matsuo, K. Suzuki, T. Fukawa, B. Li, M. Ito, Y. Shoji, T. Otani, L. Li, M. Kobayashi, M. Hachiya, Y. Tahara, D. Hashizume, T. Fukunaga, A. Fukazawa, Y. Li, H. Tsuji, K. Tamao
  Bull. Chem. Soc. Jpn. 2011, 11, 1178–1191. (DOI: 10.1246/bcsj.20110090)
  BCSJ Award Article

• Boron-Boron σ-Bond Formation by Two-Electron Reduction of a H-Bridged Dimer of Monoborane
  Y. Shoji, T. Matsuo, D. Hashizume, M. J. Gutmann, H. Fueno, K. Tanaka, K. Tamao
  J. Am. Chem. Soc. 2011, 133, 11058–11061. (DOI: 10.1021/ja203333j)
  Highlighted in RIKEN RESEARCH 2011, October, "Capturing an elusive compound" 

• A Stable Doubly Hydrogen-Bridged Butterfly-Shaped Diborane(4) Compound
  Y. Shoji, T. Matsuo, D. Hashizume, H. Fueno, K. Tanaka, K. Tamao
  J. Am. Chem. Soc. 2010, 132, 8258–8260. (DOI: 10.1021/ja102913g)
  Highlighted in RIKEN RESEARCH 2010, November, "Catching a chemical butterfly" 

• One-Pot Enantioselective Extraction of Chiral Fullerene C₇₆ Using a Cyclic Host Carrying an Asymmetrically Distorted, Highly π-Basic Porphyrin Module
  Y. Shoji, K. Tashiro, T. Aida
  J. Am. Chem. Soc. 2010, 132, 5928–5929. (DOI: 10.1021/ja910701q)

• Chirality Sensing of Fullerenes Using Cyclic Hosts Having a Chiral N-Substituted Porphyrin: a Remote Substituent Effect
  Y. Shoji, K. Tashiro, T. Aida
  Chirality 2008, 20, 420-424. (DOI: 10.1002/chir.20467)

• Solid-phase synthesis and properties of chiral peptide nucleic acids bearing cationic side chains.
  H. Harada, S. Funayama, Y. Shoji, T. Wada
  Nucleic Acids Symp. Ser. (Oxf.) 2007, 51, 259-260. (DOI:10.1093/nass/nrm130)

• Sensing of Chiral Fullerenes by a Cyclic Host with an Asymmetrically Distorted π-Electronic Component
  Y. Shoji, K. Tashiro, T. Aida
  J. Am. Chem. Soc. 2006, 128, 10690–10691. (DOI: 10.1021/ja063828f)

• Selective Extraction of Higher Fullerenes Using Cyclic Dimers of Zinc Porphyrins
  Y. Shoji, K. Tashiro, T. Aida
  J. Am. Chem. Soc. 2004, 126, 6570–6571. (DOI: 10.1021/ja0489947)
  Highlighted in C&EN, 2004, Volume 82, Issue 20, p35 in Science Concentrates

総説・解説記事など

• 有機分子・高分子の自己集合による大面積精密分子集積薄膜の構築
  福島 孝典, 石割 文崇, 庄子 良晃 
  マイクロ・ナノ熱工学の進展, エヌ・ティー・エス, 2021, p450–456 (ISBN 978-4-86043-722-0 C3042).

• 電子欠損性ホウ素化合物を利用した物質変換反応 (リンクはこちら)
  庄子 良晃, 菓子田 惇輝, 福島 孝典
  有機合成化学協会誌, 2020, Vol. 78, No.3 (3月号), p190–203.

• 電子欠損性ホウ素化合物が織りなす化学の新展開　–新化学種の創製からπ共役化合物の新合成法まで–
  庄子 良晃
  化学と工業 2016年 12月号, 1066–1067.

• Successful formation of uniform organic thin films of macroscopic size by rational space-filling design.
  Y. Shoji, T. Kajitani, T. Fukushima
  SPring-8 Research Frontiers 2015, p84–85. (open access)

• 「超ルイス酸分子」ジアリールボリニウムイオンの合成, 構造および反応性
  庄子 良晃
  月刊ファインケミカル 2015年 2月号, 59–65.

• "Simple and Strong" ジアリールボリニウムイオンの開発 ー「超ルイス酸分子科学」の開拓へ向けて
  庄子 良晃, 田中 直樹, 福島 孝典
  月刊化学 2014, Vol.69, No. 11 （11月号）, 38–42. （当該記事の閲覧が可能です。）

• 論文に見る最重要概念と革新実験データ "Taking the Aromaticity out of Aromatic Interactions"
  庄子 良晃, 福島 孝典
  CSJカレントレビュー12「未来材料を創出するπ電子系の化学」p35–37.

科研費など研究費獲得（研究代表者分）

• 科研費 基盤研究B, 19H05385, 2020-2022年度
  「電子欠損性ホウ素とπ電子系のインタープレイに基づく新物質変換反応と機能化学」

• 科研費 挑戦的研究（萌芽）, 19K22165, 2019-2020年度
  「π電子系機能物質化学の革新を招く供与性π結合エンジニアリング」

• 科研費 新学術領域研究（研究領域提案型）公募研究, 19H05385, 2019-2020年度
  「異方的構造変化を発動する自己集合化有機薄膜の創製と環境応答機能創出」
  発動分子科学 - エネルギー変換が拓く自律的機能の設計

• 科研費 基盤研究B, 17H03020, 2017-2019年度
  「ホウ素化合物による新芳香環構築反応の機構解明と機能材料開発」

• 公益財団法人旭硝子財団 自然科学系研究奨励, 2017-2018年度
  「新規化学ドーパントを用いたナノカーボンの高電導化・高分散化による新材料開発」

• 科研費 若手研究A, 26708004, 2014-2017年度
  「二配位ホウ素カチオンによる超ルイス酸分子化学」

• 有機合成化学協会コニカミノルタ研究企画賞 研究奨励費, 2014年度
  「空軌道配列の精密制御に基づく新規電子輸送システムの構築」

• 科研費 挑戦的萌芽研究, 26620058, 2014-2015年度
  「空軌道エンジニアリングによる電子輸送システムの構築」

• 科研費 若手研究B, 22750046, 2010-2012年度
  「ホウ素置換π共役化合物の創成と還元によるキノイド構造発現および共役構造制御」

招待講演

• 有機合成2月セミナー 有機合成のニュートレンド2021 (2021. 2. 5), ZOOM, 有機合成化学協会関西支部
  "ホウ素とπ電子系のインタープレイに基づく物質変換反応と機能化学"

• 第３６回高分子セミナー・Center for Functional SeNsor & Actuator (CFSN) セミナー  (2019. 10.4), NIMS: 国立研究開発法人物質・材料研究機構, つくば
  "Development of electron-deficient boron compounds and their organic transformations"

• 10th International Conference on Molecular Electronics and BioElectronics (M&BE 10) (2019. 6. 25–27)
  Kasugano Intl. Forum, Nara, Japan
  "Two-Dimensional Assembly of Propeller-Bladed Molecules Exhibiting Anisotropic and Dynamic Properties" 

• 第2回 触発型有機化学研究会 (AIKOC-2) 東京大学本郷キャンパス・分子ライフイノベーション棟 (2018.8.18)
  "ホウ素が媒介する連続反応の開発とその展開"

• 第53回 反応有機若手の会 埼玉県熊谷市ホテルヘリテイジ (2018.7.5)
  "ホウ素が媒介する連続反応の開発とその展開"

• 第2回 東工大応用化学系 次世代を担う若手シンポジウム, 東京工業大学大岡山キャンパスEEI棟 (2018. 3. 24)
  "ホウ素の特性を活かした電子・光電子機能性材料の創製"

• ITbM/IGER Chemistry Workshop 2017, 名古屋大学ITbM (2017. 11. 6–7)
  "ホウ素と芳香環で組み立てる分子機能の探求"

• 第3回「高次複合光応答」若手の会 晴海グランドホテル (2017.  9. 11–12)
  "プロペラ分子が可能にする高秩序有機薄膜の造形と機能"

• 第49回構造有機化学若手の会 夏の学校 浜名湖ロイヤルホテル(2017.  8. 3–5)
  "電子欠損性ホウ素化合物の新構造・新反応の探求"

• 第5回慶応有機化学若手シンポジウム 慶應義塾大学矢上キャンパス (2017. 4. 22)
  "電子欠損性ホウ素化合物の新構造・新反応"

• 第4回アライアンス若手研究交流会 北海道大学 (2016. 11. 9–10)
  "電子欠損性ホウ素化合物による新物質変換反応"

• 11th International Conference of Cutting-Edge Organic Chemistry in Asia (ICCEOCA-11/ARNCEOCA-2) KAIST, Daegeon, Korea (2016. 10. 27–30)
  "Novel Molecular Transformations Using Highly Electron-Deficient Boron Compounds"

• 日本化学会第96春季年会 同志社大学 京田辺キャンパス (2016. 3. 27)
  "空間充填デザインに基づく高秩序・大面積分子薄膜の構築"（特別企画講演 超分子ポリマーの精密合成：実例とヒント）

• 日本化学会第96春季年会 同志社大学 京田辺キャンパス (2016. 3. 26)
  "Synthesis, Structure, and Reactivity of Novel Electron-Deficient Boron Compounds"（第30回若い世代の特別講演会）

• 12th International Conference of Computational Methods in Science and Engineering (ICCMSE-2016) Metropolitan Hotel, Athens, Greece (2016. 3. 20)
  "Electronic Structure and Reactivity of Unprecedented Two-Coordinate Boron Cation with C–B⁺–C Bonding"

• 日本化学会関東支部栃木地区講演会 宇都宮大学 (2015. 12. 7)
  "新規ホウ素反応活性種の創製と新反応開発"

• 新学術領域「π造形科学」第二回若手研究会 大阪不死王閣（2015. 11. 20–21）
  “高秩序・大面積分子集積膜の創製：空間充填構造とビルディングブロックの設計戦略”

• Symposium on Organometallics and Organic Synthesis, Tokyo Institute of Technology, Ookayama Campus（2015. 7. 1）
  “Synthesis, Structure, and Reactivity of Diarylborinium Ions”

• The 1st International Symposium on π-System Figuration, Osaka University, Nakanoshima Center (2015. 4. 30)
  “Synthesis, Structure, and Reactivity of Two-Coordinate Boron Cation with C–B⁺–C Bonding”

• 新学術領域「π造形科学」第一回若手研究会 熱海紀州鉄道ホテル（2014. 11. 22）
  “二配位ホウ素カチオン「ボリニウムイオン」の創製　超ルイス酸分子化学の開拓を目指して“

• International Symposium on Integrated Molecular/Materials Science and Engineering (IMSE2014), Liuyuan Hotel, Nanjing, China (2014. 11. 1–3)
  "Development of Boron-based Molecular Super Lewis Acid"

• 第一回資源研フォーラム 東京工業大学 大岡山キャンパス くらまえホール （2014. 10. 21–22）
  「二配位ホウ素カチオンの創製：超ルイス酸分子化学の開拓へ向けて」

• 有機元素化学セミナー　中央大学 理工学部 応用化学科 山下研究室 （2014. 9. 27）
  「物質の新形態に基づく新機能・新現象を求めて –化学結合から分子集合体まで–」

• 京都大学 GCOEプログラム「物質科学の新基盤構築と次世代育成拠点」
  第５回 GCOE 有機若手ワークショップ（2011. 9. 12-13）京都大学北部キャンパス 
  「新奇な水素化ホウ素化合物の創製」

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お問い合わせ先

東京工業大学
科学技術創成研究院
化学生命科学研究所

当研究室は物質理工学院 応用化学系に所属しています。

教授　福島　孝典

〒226-8503
横浜市緑区長津田町4259 R1-1
電話番号:045-924-5220
FAX:045-924-5976